HEALTH CONSULTATION
Air Pathway Evaluation
SIERRA ARMY DEPOT
HERLONG, LASSEN COUNTY, CALIFORNIA
Sierra Army Depot (SIAD) is located in northeastern California, near the border of California and Nevada. SIAD currently conducts many military support activities, including receiving, storing, and distributing munitions, explosives, propellants, and other materials. Until August 2001, SIAD also used open burning (OB) and open detonation (OD) to treat, or destroy, explosives, propellants, and other materials that were considered to be waste. The OB/OD waste treatment operations generated large plumes of air contaminants that were visible from locations several miles from SIAD. These waste treatment operations ceased in 2001, due to a debate on the applicability of certain air pollution control rules.
Concerned that air emissions from SIAD might be causing adverse health effects among people who live downwind from the installation, U.S. Senator Harry Reid of Nevada submitted a petition in 2000 asking the Centers for Disease Control and Prevention to evaluate the public health implications of potential exposures to air contamination from SIAD. The request was assigned to ATSDR for response. The Agency for Toxic Substances and Disease Registry (ATSDR) has been gathering and evaluating data to address community health concerns. This health consultation presents ATSDR's response to Senator Reid's petition.
To understand community concerns, ATSDR has met with many residents from California, Nevada, the Susanville Rancheria, and the Pyramid Lake Paiute Tribe. We also have gathered data on air quality and health issues relevant to SIAD from numerous parties, including: the U.S. Environmental Protection Agency, the California Air Resources Board, the California Cancer Registry, the California Department of Toxic Substances and Control, the Nevada State Health Division, the Nevada Division of Environmental Protection, and the U.S. Army.
ATSDR believes the data we collected on air emissions, air pollution measurements, and cancer incidence paint a consistent picture of how SIAD's OB/OD waste treatment operations affected local air quality, and public health. ATSDR's two major findings for this site follow:
- Were residents in the vicinity of SIAD, both in California and Nevada, inhaling unhealthy levels of air contaminants released from SIAD's OB/OD waste treatment operations? OB/OD waste treatment operations at SIAD released many contaminants into the air, including particulate matter, metals, and chemical by-products of the waste treatment. The emissions blow primarily in the downwind direction, which is toward the east, and rarely blow west or towards Susanville. Thus, SIAD's air quality impacts in Susanville are believed to be minimal, and quite possibly not detectable. Even for the downwind directions, these emissions disperse considerably over the distance that separates SIAD from locations where people live. ATSDR reviewed findings from several modeling studies and an extensive air sampling study, all of which indicate that residents in the area have not been exposed to levels of air pollution that are associated with adverse cancer or non-cancer health effects.
- Are there more cases of cancer in the areas around the SIAD, both in California and Nevada, than are to be expected? ATSDR used two independent approaches, which rely on different data sets and are rooted in different scientific disciplines, to assess whether specific types of cancer are elevated among residents in communities around SIAD. First, our Division of Health Assessment and Consultation conducted an environmental health evaluation: they evaluated how much cancer-causing chemicals were released to the air and found that residents in the area are not breathing these chemicals at levels of public health concern. Second, our Division of Health Studies conducted a health outcome data evaluation: they reviewed descriptive data analyzed by the Cancer Registry of Northern California, Region 6 of the California Cancer Registry, which overall did not suggest evidence of excess cancers based on the cancer types analyzed in small area assessments for census tracts surrounding SIAD. However, the exception to this finding was a slight excess of leukemias (all types combined) in the Susanville area for the period 1988 through 1997a finding which did not remain statistically significant when persons with post office boxes or other non-U.S. Postal Service addresses were removed from the analysis (Section VI.C explains this process). Because Susanville is more than 30 miles upwind from SIAD, it is extremely unlikely that cancers among Susanville residents are caused by exposure to SIAD's air emissions. The data currently available from the state of Nevada does not allow for a meaningful analysis of cancer cases among Nevada residents who live downwind from SIAD.
ATSDR acknowledges that our findings for many air contaminants are based entirely on modeling analyses, which have inherent uncertainties. However, we believe the modeling analyses were rigorously conducted and likely predicted air concentrations that are higher than were actually observed. Moreover, for almost every contaminant, the estimated long-term average air concentrations were more than 100 times lower than levels of public health concern. Given this ample "margin of safety," ATSDR has confidence that basing this conclusion on modeling analyses is appropriate. Section VII provides additional information on uncertainties associated with this conclusion.
These two distinct approaches both suggest that levels of air pollution resulting from SIAD's waste treatment operation are most likely not associated with perceived elevated types of cancer among exposed populations; however, ATSDR acknowledges that the individual approaches used have inherent uncertainties and limitations.
The remainder of this health consultation explains how we reached our two major findings. Sections II through IV provide background information on SIAD and ATSDR's standard approach to evaluating environmental health issues. Sections V through VIII evaluate specific community concerns and describe how we interpreted the available air sampling, air modeling, and cancer registry data. Sections IX through XI present ATSDR's main conclusions, recommendations, and a plan for future health actions related to SIAD. Detailed technical analyses of selected issues are presented in appendices to this health consultation.
The U.S. Army (Army) owns and operates Sierra Army Depot, where many different military support activities take place. Until August 2001, a major operation at SIAD was treatment of large quantities of munitions, explosives, and propellants using open burning (OB), open detonation (OD), and incineration. SIAD's OB/OD treatment capacity was larger than that of any other military installation in the United States.
Concerned that air emissions from the treatment operations might cause health problems among nearby residents, U.S. Senator Harry Reid of Nevada wrote two letters to the director of the Centers for Disease Control and Prevention (CDC) in February 2000 requesting a study on the matter. His first letter asked that CDC investigate a perceived cancer cluster in the area around SIAD, and his second letter requested that CDC investigate other illnesses and health conditions, including birth defects, respiratory ailments, autoimmune diseases, and attention deficit disorder. The CDC director, who is also the administrator for ATSDR, referred these requests to ATSDR for further evaluation.
This health consultation presents ATSDR's response to Senator Reid's letters. Specifically, this health consultation addresses the following two key questions, which encompass the many concerns expressed to ATSDR:
- Are residents in the vicinity of SIAD, both in California and Nevada, inhaling unhealthy levels of air contaminants released from the treatment activities at SIAD?
- Are there more cases of cancer in the areas around the SIAD, both in California and Nevada, than are to be expected?
The remainder of this health consultation presents ATSDR's response to these questions. Specifically, the health consultation summarizes the information we collected on SIAD (see Section III), and then documents how we interpreted this information (see Sections IV through VIII) to reach our main conclusions (see Section IX).
To answer the two key questions, ATSDR first gathered extensive background information on SIAD, the neighboring communities, and the local environmental setting. The remainder of this section reviews this background information, which ATSDR critically evaluated to understand what contaminants SIAD released to the air, how these contaminants moved through the air, and to what levels people may have been exposed. This section focuses on facts and observations about SIAD, without analysis or interpretation. Later sections of this health consultation (particularly Sections V and VI) describe how this background information factored into ATSDR's public health evaluations.
Figure 1 shows the location of SIAD, which is in northeastern California, approximately 40 miles east-southeast of Susanville, California, and 55 miles north-northwest of Reno, Nevada. The installation spans 96,340 acres, all within Lassen County, California. The border between California and Nevada is less than 4 miles from SIAD's easternmost boundary. Most of the operations at SIAD take place on two major parcels of land, which Figure 2 shows.
- OB/OD Area. The site documents refer to the northern parcel of land shown in Figure 2 by several names, including the OB/OD Area, the Upper Burning and Detonation Area, and the Upper Burning Grounds. The remainder of this health consultation refers to this area as the OB/OD Area. This area, which spans approximately 5,350 acres, is where OB/OD activities takes place. Access to this area is restricted.
- Main Depot. The southern parcel of land shown in Figure 2 is known as the Main Depot, which spans 29,950 acres. Many operations occur at the Main Depot, including receipt and storage of munitions, incineration of certain wastes in the Deactivation Furnace, and various other military support activities. Access to this part of SIAD is also restricted.
In addition to these parcels of land, SIAD property also includes a large portion of Honey Lake. The shoreline of this lake fluctuates significantly from one month to the next, depending on the season, temperature, and precipitation levels. No routine operations occur on this part of SIAD. Access to Honey Lake is not restricted.
Several small cities and communities are located within 15 miles of the SIAD property boundary. These include, but are not limited to, Herlong and Doyle, in California, and Flanigan in Nevada. SIAD is situated in a valley, known as Honey Lake Valley, along the eastern slope of the Sierra Nevada mountains. The average elevation of this valley is approximately 4,200 feet above sea level. The Main Depot is located on the valley floor, and the OB/OD Area is located in foothills on the northern edge of the valley. The mountains that surround the valley reach much higher elevations, some higher than 7,000 feet above sea level.
The land surrounding SIAD is used for many purposes, including military, agricultural, ranching, recreation, and residential. Zoning restrictions have left much of the land immediately adjacent to SIAD largely undeveloped. Specifically, Lassen County has zoned all land within 1 mile of SIAD boundaries for general agricultural uses with a "Public Safety" restriction (DEIR 2000). This restriction requires prospective property owners to obtain special permits before building homes.
There are several additional land use restrictions in the vicinity of SIAD. For instance, the land immediately west, north, and east of the OB/OD area are federal lands managed by the Bureau of Land Management (BLM). Most of these lands are part of the Skedaddle Mountain Wilderness Study Area (WSA) (BLM 1997), where land uses are extremely limited. BLM policies, for example, indicate that "permitted activities in WSAs (except grandfathered and valid existing rights) are temporary uses that create no new surface disturbance, nor involve permanent placement of structures" (BLM 1995). Therefore, activities such as building homes and off-road driving are prohibited in the WSA.
The Skedaddle Mountain WSA extends east from the OB/OD Area to the border between California and Nevada. East of the Skedaddle Mountain WSA is the Dry Valley Rim WSA, which is located entirely within Nevada. Overall, WSA lands extend approximately 7 miles east of the OB/OD Area. East of the two WSAs and additional BLM lands is the Pyramid Lake Indian Reservation, home of the Pyramid Lake Paiute Tribe. The Reservation lands are at least 14 miles from where OB/OD operations take place.
Land uses to the south and southeast of the OB/OD area are less restricted. Outside of the "Public Safety" restriction lands, the land in this direction is primarily used for ranching, whether on privately owned lands or lands zoned as open space. The Plumas National Forest is located 15 miles southwest of the OB/OD Area. These forest lands are used for recreation, grazing, wildlife management, and other purposes.
ATSDR examines demographic data, or information on the local population, not only to determine the number of people who are potentially exposed to environmental contaminants but also to evaluate exposures for sensitive sub-populations, such as children, women of childbearing age, and the elderly.
ATSDR compiled demographic data from the U.S. Census. These data indicate that the land immediately surrounding SIAD is sparsely populated and 11,725 California and Nevada residents live within 20 miles of SIAD. Of this population, 6% are children aged 6 and younger; 7% are adults aged 65 and older; and 14% are women between the ages of 15 and 44, which ATSDR considers to be of childbearing age. A much larger population (270,580 people) lives within 50 miles of SIAD. This radius includes the entire Pyramid Lake Indian Reservation and the cities of Reno, Nevada, and Susanville, California.
When researching the demographics of the area, ATSDR also reviewed site documents to identify the specific populations living closest to the OB/OD operations. In California, the nearest residences are at two ranches, which are located 1.3 and 3.1 miles from where OB occurred (DEIR 2000). In Nevada, the nearest populated area identified in the site's risk assessment was Flanigan, which is 11.6 miles from where OB occurred (Brown and Root Environmental 1996a). As Section V describes, ATSDR considered these distances when evaluating air quality impacts from the OB/OD operations.
D. Climate and Prevailing Winds
The climate and prevailing wind patterns affect how contaminants move through the air. The Honey Lake Valley, where SIAD is located, is arid, typically getting 5 to 6 inches of precipitation per year (DEIR 2000). Temperatures in the vicinity of SIAD vary considerably with season. In the summer, daily temperatures range from 64 to 100 oF; for comparison, the average temperature in winter months is 33 ºF (DEIR 2000).
The prevailing wind patterns determine the directions where air emissions from SIAD primarily blow. Two meteorological monitoring stations, both operated by SIAD, have collected hourly observations of surface wind speeds and directions in Honey Lake Valley. These data were collected according to SIAD's Meteorological Monitoring Plan, which reportedly has been approved by the California Air Resources Board (CARB) and meets EPA requirements for regulatory applications involving meteorological monitoring (Tetra Tech NUS 2001).
Figures 3 and 4 summarize the hourly wind speed and direction measurements in a format known as a wind rose. Wind roses display the statistical distribution of wind speeds and directions in a single plot. Figure 3 presents this information for the meteorological station near the incinerator on the Main Depot property, and Figure 4 presents data for the station operated at the Break Shack in the OB/OD area. Though specific trends in wind patterns differ between these two wind roses, as is common for locations near complex terrain, both figures indicate that surface winds near SIAD predominantly blow from west to east. At the Break Shack station, for instance, winds directions during the afternoon hours, when most OB/OD operations occur, were roughly from west to east 75% of the time (TetraTech NUS 2000)(1). For this same subset of hours, winds blowing from east to west occurred only 10% of the time.
Though these observations clearly demonstrate that the prevailing pattern of surface winds is from west to east, prevailing wind patterns at the surface may differ from those aloft. How wind directions vary with altitude is an important consideration for SIAD, because plumes from OB/OD operations have been observed to rise more than 2,000 feet above the ground (Brown and Root Environmental 1996a). One study examined upper air wind patterns by placing surveillance equipment on weather balloons, which observed wind directions during the afternoon hours at several different altitudes (Tetra Tech NUS 2000). This study found that prevailing winds at all altitudes were from directions between the south and west-northwest, and winds blowing from the east were again very rare.
Overall, the prevailing wind patterns at SIAD generally blow from west to east, which would carry air emissions from SIAD predominantly toward the state of Nevada. These emissions blow toward the communities west of the installation infrequently.
Since it was constructed in 1942, SIAD has conducted various military support activities. SIAD's mission has consistently been to receive, store, transport, repair, and treat many types of munitions, explosives, propellants, and other materials. Treatment (or destruction) of these materials has been achieved primarily through OB, OD, and incineration. Although SIAD has other sources of air pollution (e.g., storage tanks, motor vehicles, boilers), this health consultation focuses exclusively on SIAD's waste treatment operations, which account for the majority of SIAD's air emissions and are most likely to transport long distances.
SIAD operated, and continues to operate, under various environmental regulations and permitting authorities. Permitting of waste management operations fell under EPA's Resource Conservation and Recovery Act (RCRA). From 1980 to 2003, SIAD operated its OB/OD operations as an "interim status" facility under RCRA. It is not uncommon for certain operations to remain under this status for many years. SIAD applied for a RCRA permit in the early 1990s. That application had been under various states of review, until SIAD officially withdrew the application in May 2003.
Air emissions from SIAD fell under the federal Clean Air Act, among other regulations. SIAD first applied for a "Title V" air permit in 1996, as required by the 1990 Clean Air Act Amendments. The installation received its first 5-year permit in 1998. In 2001, that permit was reissued with minor changes. One notable change that occurred since then resulted from a legal settlement that prevented SIAD from conducting routine OB/OD operations. Since 2001, the installation has been permitted to use OB/OD only under emergency situations or for national security reasons.
The rest of this section describes key features of SIAD's waste treatment operations:
- What waste materials has SIAD treated? SIAD has treated a wide range of waste materials, both from military and non-military waste generators. The materials include bombs, warheads, rocket motors, propellant charges, grenades, and mines, all of which contain different components (e.g., metal casings, explosive charges, propellants). The materials are considered to be "waste" for various reasons: they may have exceeded their shelf-life, they may not have been built to specifications, or they may have become obsolete. Though SIAD has treated a wide range of conventional weapons, it has not treated nuclear, chemical, or biological weapons, and does not treat radioactive wastes. Site documents state, for example, that "radioactive items, including depleted uranium rounds, are not treated [in the OB/OD area] under any circumstance" (DEIR 2000).
- How much waste material has SIAD treated? The amount of waste material SIAD treated varied from year to year. Until August 2001, the installation's waste treatment permit allowed SIAD to destroy 30,000 tons of waste material in OB/OD operations per year (DEIR 2000), but the actual amounts of waste treated were typically lower. Figure 5 shows the total amount of waste material that SIAD treated per year from 1990 to 2001.
- What waste treatment technologies did SIAD employ? The text box on the following page describes, in general terms, how OB, OD, and incinerations destroys wastes, and the remainder of this section explains how these operations were specifically applied at SIAD.
- OB waste treatment operations. According to site documents, SIAD first used OB to treat waste materials in 1950 (DEIR 2000), and this practice continued until 2001. The nature and extent of OB activities peaked during the 1990s. Site documents provide extensive insights on OB activities in more recent years.
- OD waste treatment operations. Like the OB operations, OD operations first began at SIAD in 1950 (DEIR 2000). In the 1950s, only small amounts of ammunition were treated at the installation, and these amounts came from the installation's existing stockpile. In the 1960s and 1970s, the treatment activity increased, and approximately 20 employees worked seasonally on the OB/OD grounds. During this time, however, the installation still treated only waste materials from the installation's existing stockpile. In the early 1980s, SIAD was designated one of the primary demilitarization sites for OB/OD. From the early 1980s through 2001, ammunition started being shipped to SIAD for OB/OD treatment. In the late 1980s, approximately 60 employees worked on the OB/OD grounds (Holsey 2003). The OB/OD treatment activity peaked in the 1990sthe time frame shown in Figure 5.
- Incineration waste treatment operations. Site documents indicate that SIAD has operated two incinerators on the Main Depot since 1942. One incinerator treated waste materials from 1942 until it was dismantled in the mid-1950s (DEIR 2000). Since little information is available on the design of this incinerator and the amount and types of wastes that it treated, and exposures to air emissions from this operation ceased approximately 50 years ago, this health consultation does not address this incinerator further.
- When did the waste treatments occur? SIAD treated wastes at various times during the year, but primarily during the spring, summer, and fall. OB/OD waste treatments were limited to the daytime hours. SIAD implemented several standard operating procedures that further limited when waste treatments would occur. These limitations prohibited treatments from occurring during thunderstorms or on days with calm winds, limited visibility, or air quality alerts (Brown and Root Environmental 1996a).
The amounts treated in 2001 are the lowest for the time frame considered, because the facility ceased all treatment operations in August 2001, when Lassen County Air Pollution Control District informed SIAD that continued OB/OD operations would be considered a violation of the district's air quality regulations. Since August 2001, the only OB/OD operations that have been permitted at SIAD are those for emergency purposes or national security reasons.
Between 1990 and 2000, the installation treated an average of 19,000 tons of waste material (gross weight, see text box) per year, or 64% of the maximum treatment amount allowed by its permit. Site statistics suggest that OD operations accounted for the majority of the waste material treated, but the relative amount treated by OB, OD, and incineration changed from year to year. Until routine OB/OD operations ceased in August 2001, SIAD had the largest OB/OD treatment capacity of all military installations in the United States (DEIR 2000).
These activities occurred exclusively in the OB/OD Area (see Figure 2). OB occurred both in "pits" and "pans," as described below.
OB pans are made of carbon steel and were used primarily for treating smaller quantities of solid propellants, which typically contained nitrocellulose, nitroglycerine, and nitroguanidine in greatest quantities. Most pans are between 15 and 20 feet long, and up to 8 feet wide. Before OB operations ceased in 2001, SIAD operated 150 burn pans, which were divided among 30 burn stations. Permit requirements limited SIAD to burn no more than 1,000 pounds of NEW in these pans during each event. These burns typically lasted 2 minutes or less, after which waste ash was collected and handled according to solid waste management requirements.
OB was conducted in pits to treat much larger quantities of propellantsup to 160,000 pounds of NEW during a single event. These OB operations, which were primarily used to treat large rocket motors, generally lasted up to 10 minutes, but some took longer due to the large amount of propellants being treated. The principal materials treated in these operations include ammonium perchlorate and nitroglycerine. Residual ash and rocket motor casings left after such OB events were collected, recycled, or disposed of according to solid waste management regulations.
All OD operations took place in the OB/OD Area (see Figure 2) in 14 pits, which were dug into the sides of hills. For each detonation, waste material is placed into the pit and then detonated from a safe distance. SIAD was allowed to conduct up to two detonations per day in each pit, and each detonation could treat no more than 10,000 pounds of NEW (DEIR 2000). SIAD personnel collected and recycled scrap metals that remain after the detonations.
SIAD constructed another incinerator, known as the Deactivation Furnace, on the Main Depot. This incinerator treated waste material from 1971 until 1989, after which it was closed for 3 years while SIAD obtained the appropriate operating permits. In 1992, the incinerator began operating again, but only to treat wastes classified as "non-hazardous" by EPA's waste management regulations (DEIR 2000). These non-hazardous wastes include small arms munitions, fuzes, some grenades, and detonators. The incinerator treats far less quantities of waste materials than the OB/OD operations. In 1996, for instance, SIAD treated 6 tons of non-hazardous waste munitions by incineration, which accounted for less than 0.1% of the total waste material treated at the depot.
The incinerator is equipped with air pollution controls, including a cyclone and a baghouse, that reduce the amount of pollution released to the air. Site documents suggest that these controls reduce air emissions of several metals (barium, chromium, lead, antimony, beryllium) by more than 99% (DEIR 2000), while others (copper, manganese, nickel) are controlled less effectively.
Though these operating procedures likely reduced air quality impacts from OB/OD operations, recent press accounts reported that SIAD did not always adhere to the procedures (Reno Gazette-Journal 2000). ATSDR notes that the operating procedures were internal guidelines, not statutory requirements of air permits. The frequency with which the standard operating procedures were not followed is not known.
The previous paragraphs provide relevant background information on the three waste treatment operations that SIAD has recently employed. Section V refers to this background information when evaluating the air quality impacts of contaminants released by these operations.
F. Other Sources of Air Contaminants
When evaluating the air exposure pathway, ATSDR not only considers emissions from the sources of concern (in this case, OB/OD operations at SIAD), but also considers emissions from other sources in the area. We do this because community members ultimately are exposed to air contaminants from all local sources, not just those from one or two.
The area surrounding SIAD is sparsely populated and contains few air emissions sources, especially when compared to urban and industrial settings. The Lassen County Air Pollution Control District has estimated emissions from major industrial sources (DEIR 2000), but most of the sources identified are at least 10 miles from SIAD. Air emissions sources in the vicinity of SIAD are limited, and include wind-blown dust and motor vehicle exhaust.
With one exception, which is discussed in the following paragraph, air emissions from SIAD's OB/OD operations far exceed those from all other local sources. Recent press accounts have acknowledged this (Sacramento Bee 2001), citing air emissions data that SIAD submitted to EPA's Toxic Release Inventory (TRI). Specifically, the TRI data EPA originally released for reporting year 1999 indicate that SIAD emitted more air emissions of toxic chemicals than did any other industrial or federal facility in the state of California (EPA 2001). SIAD has since revised its air emissions estimates, and the installation's emissions no longer rank among the top 100 in the state (EPA 2002a). Section V.A of this health consultation discusses this revision in TRI data in greater detail.
Other than SIAD, one notable emissions source that has been found to affect local air quality is wildfires. SIAD can expect to experience several small wildfires annually in the area surrounding the installation; these fires are caused either by lightning or human activity. The area typically experiences one or two large wildfires each year at some location within a 60-mile radius of the installation (Holsey 2003). According to EPA emissions data, a wildfire in California can release over 150 tons of particulate matter to the air per day,(2) in addition to releasing various other contaminants (EPA 1996). Because wildfires release large amounts of contaminants over short time frames, emissions from wildfires often far outweigh those from all other local sources combined. This trend was recently observed during an ambient air monitoring program at SIAD, when some of the highest levels of air pollution detected occurred when a wildfire burned out of control in the nearby Feather River Canyon (TetraTech NUS 2001). Section V.C revisits this issue.
Overall, during the 1990s, OB/OD operations at SIAD were clearly the dominant local air emissions source over the long term; however, emissions from wildfires during that time still exceeded those from all other sources near SIAD over short time frames. Since 2001, OB/OD operations at SIAD have had only minimal air quality impacts in the area.(3) Section V of this health consultation evaluates the public health implications of all air emissions sources in the vicinity of SIAD.
Since receiving Senator Reid's letters in February 2000, ATSDR has conducted many activities to identify community concerns, understand the local environmental setting, and evaluate air quality impacts from SIAD's waste treatment operations. These activities began with a site tour in June 2000, when ATSDR environmental health scientists and community involvement specialists visited SIAD, at a time when waste treatment operations were occurring. Our staff members met with local community members, tribal government officials from the Susanville Rancheria in California and the Pyramid Lake Paiute Tribe in Nevada, and other groups. We also met separately with representatives of the California Cancer Registry of Northern California and of the Nevada Bureau of Disease Control and Intervention. Following the site visit, ATSDR developed and distributed a fact sheet describing our involvement with the site.
From October 2000 through the present, ATSDR environmental health scientists have been obtaining and interpreting site documents. Several critical developments have occurred during this time, including the release of the only ambient air monitoring study conducted during OB/OD waste treatment activities (TetraTech NUS 2001) and the cessation of routine OB/OD activities in August 2001. ATSDR considered information published as recently as August 2002 when preparing this health consultation.
H. Quality Assurance and Quality Control
ATSDR reviewed and evaluated information provided in the documents referenced in Section XIII. The environmental data presented in this health consultation were taken from reports and analyses produced by many parties, including EPA, SIAD, the California Cancer Registry, the Nevada State Health Division, and others. The limitations of these data have been identified in the associated reports, and they are restated in this document, as appropriate. After reviewing the studies conducted to date, ATSDR determined that the quality of environmental data available in the site-related documents for SIAD is adequate to make public health decisions, except as otherwise noted. Sections V and VI present ATSDR's specific conclusions regarding the quality of the air sampling and modeling studies and cancer registries and describe how these different studies' findings factored into our conclusions.
ATSDR also used an extensive review process for quality control purposes and to ensure that our evaluations are scientifically sound. The review involved numerous parties, including ATSDR scientists, state environmental and health agencies, and lead authors of several studies cited in this report. Our final health consultation will be issued after we have received and addressed all comments.
This section of the health consultation addresses the inhalation exposure pathway to air contaminants, focusing specifically on where air emissions from SIAD go and who might come into contact with them. Analyzing exposure pathways is important because:
- If people are not exposed to a site's environmental contamination, then the contaminants cannot pose a public health hazard and additional analyses are not necessary.
- If people are exposed to site-related contamination, then further analysis is needed to characterize that exposure. Just because exposure occurs does not mean that people will have health effects or get sick. In fact, for many chemicals, environmental exposures are often far lower than the exposures that people experience through their diets and perhaps through their occupations. Several questions must be answered to understand the public health implications of exposure: To what chemicals are people exposed? How often are people exposed, and for how long? At what levels are people exposed? These are just some of the issues that ATSDR considers when assessing whether harmful health effects might result from exposure.
The remainder of this section describes how ATSDR assessed inhalation exposures for communities near and downwind from SIAD (Section IV.A) and reviews the process ATSDR used to evaluate the inhalation exposures (Section IV.B).
A. Who Is Potentially Exposed to SIAD's Air Emissions?
One of the first steps in ATSDR's health consultation process is to identify populations that are definitely or potentially exposed to a site's contamination. We do this by reviewing five elements that together make up an exposure pathway. These five elements, and how they relate to air emissions from SIAD, follow:
- Source of contamination. A source of contamination must exist in order for exposures to occur. The OB/OD waste treatment activities at SIAD released large quantities of air pollutants. Thus, a source of contamination clearly existed for this site.
- Environmental media and transport. People cannot be exposed unless contaminants move from their source or origin through the environment to an exposure point. A recent air sampling study at SIAD found that emissions from the OB/OD area affected air quality at locations within 5 miles of the installation boundary (see Appendix C.1), but it is difficult to determine exactly how far away actual air quality impacts occurred. We recognize that most dispersion models predict that emissions sources generally have air quality impacts for many miles downwind, but the magnitude of these impacts often is far too small to measure.
- Point of exposure. Exposure cannot occur unless contaminants reach a location where people have access. The main modeling study published for this site predicts that some contaminants from the OB/OD area can transport to most locations in the Honey Lake Valley, so a point of exposure clearly exists.
- Route of exposure. For exposure to occur, people must contact chemicals in a contaminated media, either through inhalation, ingestion, or dermal contact. Inhalation exposures clearly occur if air contamination is present.
- Potentially exposed population. Ultimately, people must come into contact with chemicals at the point of exposure in order for ATSDR to conclude that exposures have occurred. Our analyses of demographics in California and Nevada confirm that people live within the 50-mile radius that is the focus of this study, thus the condition of a potentially exposed population is met.
Knowing that residents who live more than 20 miles away from SIAD have expressed concern about the OB/OD emissions, ATSDR decided to consider all populations within a 50-mile radius as potentially exposed. This decision does not mean that everyone within 50 miles of SIAD is actually exposed to the air emissions. It is rather a decision we made to frame the analyses for this health consultation. We use the term potentially exposed because the available air sampling and modeling studies suggest that air concentrations resulting from SIAD's emissions are quite limited and perhaps not detectable beyond 10 miles from the OB/OD area. Thus, this health consultation only examines the possibility that residents who live within 50 miles of SIAD are exposed to the OB/OD emissions.
By focusing our analyses on a 50-mile radius, we include among the potentially exposed populations residents as far upwind as Susanville, CA, and as far downwind as the Pyramid Lake Indian Reservation. On the other hand, we are assuming that residents of Reno, Nevada, are not exposed to the OB/OD air emissions. ATSDR based this decision on its experience evaluating other sites where residents are concerned about long-range atmospheric transport of emissions and on two site-specific observations: Reno is not in the prevailing downwind direction from SIAD (see Figures 2, 4, and 5), and past air quality problems in Reno have been attributed primarily to emissions sources found in the Reno area (see Appendix C.3).
Section V describes how we reviewed the available air sampling and dispersion modeling studies to assess the health implications of potential exposures to air contaminants released by SIAD.
ATSDR used established methodologies to determine the public health implications of exposure to air contaminants from SIAD. Specifically, we followed a three-step approach when addressing the potential exposures described previously: (1) identify concentrations of contaminants released to the air, (2) select chemicals for further evaluation by screening the concentrations against health-based comparison values, and (3) perform toxicologic evaluations for those contaminants selected for further evaluation.
The first step involves tabulating air concentrations for site-related contaminants. ATSDR prefers to use actual measurements (i.e., air sampling results) for this step, rather than relying on engineering calculations or predictions from air quality models. This preference results from the fact that air quality models estimate ambient air concentrations, sometimes with great degrees of uncertainty, while sampling studies measure ambient air concentrations. However, air quality models are critical tools in cases when exposures may have occurred during time frames when, and at locations where, sampling did not. Section V.C reviews our best estimates of exposure concentrations. Our evaluation includes different averaging times: 24-hour average levels are used to evaluate acute exposures (i.e., those that occur over the short-term), while annual average levels are used to evaluate chronic exposures (i.e., those that occur over the long-term). The ambient air concentrations presented in Section V.C draw from the best available information for this site, which is a combination of measured and estimated air contamination levels.
The second step in evaluating exposure pathways is selecting contaminants for further evaluation. This is accomplished by comparing the ambient air concentrations for site-related contaminants to health-based comparison values. Comparison values are developed from the scientific literature concerning exposure and health effects. To be protective of human health, most comparison values have large safety factors built into them. For some chemicals, the safety factors are quite large (a factor of 100 or greater). As a result, ambient air concentrations lower than their corresponding comparison values are generally considered to be safe and not expected to cause harmful health effects, but the opposite is not true: ambient air concentrations greater than comparison values are not necessarily unhealthy levels of air pollution. Rather, chemicals with concentrations higher than comparison values require further evaluation. Chemicals without published health-based comparison values are automatically considered as requiring further evaluation. The text box on the following page presents the approach ATSDR used to select comparison values for this health consultation.
The final step in the assessment methodology is evaluating the public health implications of exposure to any contaminants identified as requiring further evaluation. For these contaminants, ATSDR puts the public health implications of exposure into perspective by considering site-specific exposure conditions and interpreting toxicologic and epidemiologic studies published in the scientific literature. Thus, this step is a state-of-the-science review of what the exposure levels mean in a public health context.
V. EVALUATION OF AIR EXPOSURES
To assess potential air exposures for this site, ATSDR addressed three questions: What contaminants did SIAD release to the air (Section V.A)? How did these contaminants move through the air to where people live (Section V.B)? Were residents exposed to contaminants at levels that might cause adverse health effects (Section V.C)? The answers to these questions were important factors to consider when addressing community concerns regarding cancer (Section VI), because the exposure evaluations tell us which populations were exposed, to what chemicals (including carcinogens), and for how long.
A. What Contaminants Did SIAD Release to the Air?
To characterize air emissions from SIAD, ATSDR first identified contaminants that are released to the air and then obtained estimates for the rates at which these emissions occur. An important first step in this process was to understand exactly what happens during typical OB/OD operations. Figure 6 illustrates what emissions occur during a typical OD event. Referring to this figure, the following paragraphs identify the categories of contaminants released to the air, and describe qualitatively how emissions may differ between OD and OB.
- Particulate matter (PM). As Figure 6 shows, OD events are explosions at ground level. The explosions release large amounts of energy, which cause some of the nearby soils and fragments from the waste material to eject to the air. Much of the soils and fragments that become airborne fall back to the ground near the OD pit, but some particles (or PM) remain airborne and can transport downwind. Though Figure 6 depicts a typical OD event, PM emissions also occur when rocket motors are burned and during OB events. OB of wastes in burn pans release a smaller quantity of PM, because the energy released during the waste treatment does not cause large quantities of soils to become airborne.
- Metals and inorganic compounds. During an OD event, metals and other inorganic materials may be emitted from several sources. For instance, metallic casings from munitions fragment after a detonation, and some fine particles containing these metal fragments can become airborne. Further, the soil ejected into the air in an OD event contains metals, both naturally occurring metals and those that remain in the soil from past releases. Finally, some mixtures of explosives and propellants contain metals, such as aluminum dust, which can become airborne during an OB/OD event. Table 1 lists the metals that are most commonly emitted from SIAD's OB/OD operations.
- Explosives, propellants, and fillers. The explosives and propellants in the waste material essentially provide the "fuel" for the OB/OD events. In OD, for example, explosives are remotely detonated, which then triggers the chemical reactions that rapidly consume these materials and any other organic fillers in the waste. These chemical reactions release large amounts of energy as the chemical bonds from the explosive and propellant molecules break, thus forming smaller, more stable molecules, such as water and carbon dioxide. Data collected during OB/OD events conducted in controlled settings suggest that more than 99.9% of explosives and propellants in munitions waste are typically destroyed during waste treatment (Bjorklund et al. 1998; Brown and Root Environmental 1996a). In other words, OB/OD destroys almost all of the explosives, propellants, and fillers in waste munitions, but small amounts of these chemicals are released to the air. Table 1 lists the explosives, propellants, and fillers found in largest quantities in the waste material treated at SIAD.
- OB/OD chemical by-products. During OB/OD events, chemical reactions not only consume the explosives, propellants, and fillers, but they also form numerous organic and inorganic chemical by-products. The overwhelming majority of these by-products are relatively benign from a public health perspective. Examples include water vapor, nitrogen, and carbon dioxideall of which are relatively abundant in the atmosphere. However, incomplete combustion of the waste material also generates trace amounts of toxic chemicals. Table 1 lists the OB/OD chemical by-products believed to be released in greatest amounts by SIAD's waste treatment operations.
The chemical composition of the waste being treated largely determines the chemical by-products released from a given event. The materials treated by the majority of OB/OD operations are explosives and propellants, most of which are molecules containing carbon, nitrogen, oxygen, and hydrogen. To a first approximation, the chemical by-products will also be composed of these elements. OB of rocket motors, on the other hand, has notably different emissions because the propellants contain high levels of chlorine and aluminum. ATSDR considered this when evaluating the public health implications of the air emission rates.
Although Table 1 identifies the contaminants that SIAD's waste treatment operations release in greatest quantities, the actual amounts of contaminants released to the airor emission ratesare better indicators of the potential air quality impacts of a given source. ATSDR obtained air emissions data for SIAD from two sources: EPA's Toxic Release Inventory (TRI) and the human health risk assessment SIAD prepared for its air permit application (Brown and Root Environmental 1996a). More information on these data sources follows.
Table 2 presents the air emissions data that SIAD reported to TRI. SIAD's original air emissions data submitted to TRI received local press attention for being higher than those for any other facility in California (Reno Gazette-Journal 2001b); however, SIAD has since submitted revised data and the installation no longer ranks among the state's top 100 polluters. The revised TRI submission had dramatically lower emissions estimates for aluminum, copper, and zinc. Fortunately, ambient air monitoring data are available for these metals, and the measured concentrations (see Section V.C) strongly suggest that SIAD's original TRI submissions are indeed gross overestimates of the installation's actual air emissions. (The text box, on the following page, provides additional information on the recent changes to SIAD's TRI emissions estimates.)
In addition to the emissions data SIAD submitted to TRI, the installation has recently reported air emissions data for nearly 100 air contaminants in a human health risk assessment prepared to accompany a permit application (Brown and Root Environmental 1996a). Table 1 identifies all contaminants with estimated emissions rates greater than 10 pounds per year. Appendix D.1.1 describes how these emission rates were estimated, and presents ATSDR's critical review of the emissions estimation algorithm. ATSDR found that the emissions data reported in the human health risk assessment are based on several conservative assumptions that likely overstate actual emission rates. The remainder of this section addresses the potential air quality impacts from the contaminants listed in Tables 1 and 2 (and others considered in the human health risk assessment).
B. How Did the Contaminants Move through the Air?
Although SIAD's waste treatment operations have released numerous pollutants in varying quantities, it does not necessarily follow that all residents in the area have been continuously exposed to the pollutants listed in Table 1. In fact, the air emissions will disperse greatly over the distance that separates the OB/OD area from the nearest residential locations. Local meteorological conditions largely determine where SIAD's air emissions blow and how rapidly they disperse.
As Section III.D explains, the prevailing surface wind direction at SIAD is from west to east, and winds rarely blow from east to west (see Figures 3 and 4). The prevailing wind direction therefore blows waste treatment emissions from SIAD over the Skedaddle Mountain WSA toward the state of Nevada. Winds may also blow SIAD's air emissions in other directions, but this occurs far less frequently. For instance, wind direction observations suggest that winds during the afternoon hours, when most OB/OD operations occur, blow from east to west roughly 10% of the time. This trend suggests that air emissions from approximately 1 out of every 10 days with OB/OD operations will blow toward the California communities of Milford, Wendel, and Susanville. Qualitatively, SIAD's air emissions affect these cities infrequently.
Air models can provide quantitative insights of how SIAD's emissions move through the atmosphere to downwind locations. ATSDR and multiple California agencies critically reviewed modeling studies conducted by contractors to SIAD. Appendix D summarizes in detail ATSDR's critical review of the accuracy and validity of the available modeling studies. As Appendix D indicates, ATSDR believes the modeling studies provide useful information on upper-bound exposure concentrations for residents who live near SIAD. The modeling analyses report that emissions from SIAD's waste treatment operations have their greatest impacts in the unpopulated, mountainous region, directly east of the OB/OD area (TetraTech NUS 2000). The residential locations believed to have the highest air quality impacts are Skedaddle Ranch (California) and Flanigan (Nevada) (Brown and Root Environmental 1996a). The following section evaluates whether air pollution at these and other locations reached levels known to be associated with adverse health effects.
C. What Are the Public Health Implications of the Air Pollution Levels?
ATSDR thoroughly reviewed available air sampling data and air modeling data to evaluate the public health implications of exposures to SIAD's air emissions. Our technical reviews of the available sampling and modeling studies are included as Appendix C and D, respectively. We evaluated potential air quality impacts for nearly 100 chemicals, and considered the best available information on acute (or short-term) exposures and chronic (or long-term) exposures. Detailed findings, organized by category of air pollutant, follow:
- Particulate matter. Modeling and sampling studies have estimated and measured ambient air concentrations of particulate matter in the vicinity of SIAD. Both types of studies characterized particulate matter in terms of PM10, or airborne particles and droplets with diameters smaller than 10 microns. The available data suggests that ambient air concentrations of PM10 do not reach levels of health concern where people live, with elevated short-term levels occurring only in the uninhabited areas immediately east of the OB/OD area.
- Metals and inorganic compounds. Consistent with the approach used to evaluate air concentrations of particulate matter, ATSDR reviewed available modeling analyses and sampling results to assess inhalation exposures to metals and inorganic compounds, considering both long-term and short-term exposures.
- All estimated air concentrations in the dispersion modeling analysis are based on the assumption that SIAD treated the maximum amount of waste materials allowed by its air permit. Actual waste management data, however, indicate that SIAD treated approximately 2/3 of the maximum allowed amounts.
- Emissions data for metals were estimated by assuming that the entire weight of bomb casings vaporize during OD operations, even though considerable amounts of metal fragments fall to the ground following OD events. This assumption caused the air model to overstate air concentrations of metals.
- Ambient air concentrations measured during the recent air sampling study (TetraTech NUS 2001) were consistently lower than the values predicted by the dispersion modeling analysis. For instance, the highest average ambient air concentrations of aluminum and iron out of all sampling locations considered were 0.76 and 0.85 g/m3, respectively(6). These values are roughly a factor of two or more less than the average levels predicted by the models. This comparison suggests that the concentrations calculated by the dispersion model (Table 3) are higher than actual exposure concentrations.
- With three exceptions, the estimated air concentrations listed in Table 1 are more than 100 times lower than the corresponding health-based comparison values. Therefore, even if the emissions estimates used in the dispersion modeling analysis understate actual emissions by a large factor (as much as 100), the estimated air concentrations would still be lower than levels of public health concern. (As Appendix D explains, however, ATSDR believes the modeling analysis actually overestimated air emissions of metals.)
- Explosives, propellants, and fillers. ATSDR evaluated potential air quality impacts of 18 chemicals that comprise the explosive and propellant charge in the majority of waste materials that SIAD treats. Our evaluation for these chemicals is based entirely on modeling results, because no sampling studies have been conducted to measure actual ambient air concentrations of these contaminants. Although ATSDR would prefer to base these conclusions on measurements, the lack of sampling data is not a critical data gap because OB/OD waste treatment operations destroy the majority of the explosives, propellants, and fillers in the waste materials, rather than causing them to be released into the air. In fact, the large plumes that form following OB/OD events result largely from the energy released when chemical bonds in explosives and propellants are broken.
- OB/OD Chemical By-Products. As explained previously, OB/OD events break explosives and propellants into much smaller molecules, thus releasing large amounts of energy. The majority of chemicals formed during these events are relatively benign. Incomplete combustion of the explosives and propellants form trace amounts of other chemicals, including a wide range of volatile organic compounds and semi-volatile organic compounds. Table 5 lists 55 chemicals that have been identified in OB/OD tests conducted in controlled settings (see Appendix D.1). ATSDR evaluated whether ambient air concentrations of these 55 chemicals reach levels of public health concern near SIAD.
Regarding long-term exposures, a dispersion modeling analysis for the human health risk assessment (see Appendix D.1) predicted that SIAD's waste treatment operations would cause relatively small increases in PM10 concentrations at most places where people live (Brown and Root Environmental 1996a). The model suggests that SIAD's air emissions would cause PM10 levels to increase by 11 g/m3 at the Skedaddle Ranch in California and by 2 g/m3 at Flanigan, Nevada. These two locations were predicted to have the greatest air quality impacts from SIAD's emissions. Given that average "background" PM10 levels in remote areas typically fall between 20 and 25 g/m3 (EPA 2002e), the modeling analysis suggests that actual annual average PM10 levels were likely no greater than 36 g/m3 (at Skedaddle Range)a level that is considerably lower than EPA's health-based air quality standard (50 g/m3) for exposures to particles of this size. Moreover, it is important to note that these predicted increases would occur only if SIAD operated at its maximum capacity, which never occurred. As a result, the predicted air quality impacts were likely greater than what was actually observed. In summary, long-term average PM10 concentrations estimated by the dispersion model are not of public health concern.
Results from air sampling studies support the findings of the modeling analysis. First, a recent field study at SIAD (TetraTech NUS 2001) collected nearly 250 PM10 air samples at 12 locations near the installation; three of the sampling locations were designated as being near populated areas (Susanville, Patton Village, Pyramid Lake) and two locations were near Skedaddle Ranch. As Appendix C.1 explains, ATSDR believes that the field study adequately characterized air quality impacts from typical OB/OD operations at places where people live.(4) Based on 22 days with valid air samples, the average PM10 levels were 26 g/m3 in Susanville, 19 g/m3 in Patton Village, and 26 g/m3 at the Pyramid Lake Indian Reservationall lower than EPA's annual average health-based standard. Further, at the two sampling locations closest to Skedaddle Ranch, average PM10 levels were 28 and 35 g/m3. Therefore, both predicted and measured long-term average concentrations of PM10 in residential locations are not at levels of health concern. It is important to note here that this recent sampling study characterized air quality impacts during what were once typical operation activities at SIAD, and not during a time when OB/OD operations were at a lull. Refer to Appendix C and D for more information on the monitoring and modeling studies that support our finding.
ATSDR also examined the public health implications of estimated and measured short-term ambient air concentrations of PM10. According to the most extensive modeling study for SIAD (Brown and Root Environmental 1996a), the highest 1-hour average PM10 concentration predicted for a residential location was 18,300 g/m3, at Skedaddle Ranch in California. As Appendix D.2 explains, ATSDR believes this modeling prediction grossly overstates actual ambient air concentrations because the model evaluated a highly unrealistic waste treatment scenario. Specifically, the short-term peak concentrations were calculated assuming that SIAD simultaneously treats waste material in all 14 OD pits and in all 30 OB burn pans, that the amounts of wastes simultaneously treated are the maximum allowed in the installation's air permit, and that this maximum treatment scenario occurs in the hour with the least favorable meteorological conditions for atmospheric dispersion. Because this combination of events is not expected to ever occur at SIAD, ATSDR concludes that the short-term modeling predictions are not representative of actual exposure conditions.
ATSDR's conclusion regarding short-term exposures to PM10 is therefore based on the available sampling results. During the 2000 air sampling study at SIAD, only 2 of the 238 valid 3-hour average PM10 measurements (or 0.008%) exceeded EPA's 24-hour average health-based air quality standard (150 g/m3). The two elevated PM10 concentrations (156 and 288 g/m3) were observed in the mountainous, uninhabited lands east of the OB/OD area.(5) The highest PM10 concentration measured in or near residential locations was 100 g/m3, which is considerably lower than EPA's 24-hour average health-based standard (150 g/m3). Therefore, the sampling data indicate that actual short-term PM10 levels in or near where people live were lower than the levels of health concern. In fact, as Figure 7 shows, the sampling data strongly suggest that air emissions from local wildfires have a much greater impact on PM10 levels in the residential locations near SIAD than did air emissions from the installation's waste treatment operations.
Overall, the best available data for the site indicate that SIAD's air emissions do not cause PM10 concentrations to reach levels of public health concern over the long term. The data further suggest that PM10 levels over the short term also are not at levels of health concern. This latter observation, however, is based on air samples collected during typical waste treatment operations. Should SIAD in the future be allowed to treat larger amounts of wastes than were treated during the sampling program, further air sampling during waste treatment operations will be needed to ensure that residents are not exposed to PM10 at levels of public health concern. Section X of this health consultation provides additional detail on ATSDR's recommendation for additional air sampling.
Table 3 lists the highest annual average air concentrations of metals and inorganic compounds predicted by SIAD's models for residential areas in California and Nevada. None of the estimated concentrations are higher than health-based comparison values, which suggests that chronic inhalation exposures to the metals and inorganic compounds in SIAD's air emissions are not of public health concern. Although concentrations predicted by air models have inherent uncertainties, several observations assure ATSDR that actual exposures to metals would not cause adverse health effects among nearby residents:
As the three exceptions, predicted concentrations of aluminum, hydrogen chloride, and manganese were all less than a factor of 10 lower than their corresponding health-based comparison values. Ordinarily, this lower margin of safety might cause ATSDR to question whether the modeling analysis is an adequate basis for reaching a conclusion. However, ATSDR notes that these three contaminants were evaluated in the recent air sampling study, and every measured concentration of these contaminants at every sampling station was lower than the health-based comparison values listed in Table 3.
For these reasons, ATSDR has confidence that long-term average inhalation exposures to SIAD's emissions of metals and inorganic compounds, as characterized by model predictions and air quality measurements, are not at levels of public health concern.
ATSDR also assessed whether short-term exposures to elevated levels of metals and other inorganics would be expected to cause adverse health effects among people who live near SIAD. Because ATSDR believes the modeling analysis grossly overstates short-term air quality impacts (see Appendix D.2), we based the acute exposure assessment on the available sampling data for the following analytes: aluminum, barium, cadmium, chloride, copper, iron, lead, manganese, nickel, and zinc. Overall, the recent air sampling study reported more than 200 valid sampling results for each of these metals and other inorganics. With the exception of barium, not a single measured concentration exceeded the health-based comparison value for chronic exposures (i.e., those listed in Table 3), which strongly suggests that none of these chemicals are found at ambient air concentrations that would be acutely toxic to humans.
In the case of barium, the highest ambient air concentration measured out of 238 valid observations was 0.911 g/m3, or less than a factor of two higher than the lowest health-based comparison value for chronic exposures. Although the effects of inhalation exposures to barium have not been extensively studied, ATSDR does not believe one-time inhalation exposures to 0.911 g/m3 of barium will be associated with health effects. This judgment is based on an occupational study of workers who used barium-containing welding rods. The study found no evidence of exposure-related health effects among individuals who inhaled average barium levels as high as 4,400 g/m3 (Zschiesche et al. 1992)or exposure levels more than 1,000 times greater than the highest measured concentration near SIAD.
Overall, our evaluations of air emissions of metals and other inorganic materials indicate that residents who live near SIAD are exposed to trace amounts of these contaminants, but the exposure levels are far below those known to be associated with adverse health effects.
Table 4 lists the estimated annual average concentrations of the 18 chemicals evaluated in SIAD's human health risk assessment (Brown and Root Environmental 1996a). For the 12 chemicals that have published health-based comparison values, the estimated annual average air concentrations were all more than 100 times lower than the most conservative comparison value, including those derived for cancer outcomes. Although modeling results likely do not equal actual exposure concentrations, ATSDR believes it is highly unlikely that the modeling analysis underestimates actual exposures by more than a factor of 100. Thus, ATSDR has confidence that actual exposure concentrations of explosives, propellants, and fillers are not greater than levels of health concern.
No health-based comparison values are available for six of the chemicals listed in Table 4; however, the estimated concentrations of these chemicals are extremely low. With the exception of nitrocellulose, for example, the highest annual average concentrations of the chemicals at any residential receptor are all estimated as being less than 0.001 g/m3 (or 1 ng/m3). ATSDR has found no evidence in the scientific literature that any of the chemicals would be toxic at these exposure levels; however, we acknowledge that a limited set of toxicity studies have been conducted on these chemicals. In the case of nitrocellulose, the highest estimated exposure concentration at a residential location was 0.0041 g/m3. These levels are not expected to be toxic to humans, based on the limited ingestion toxicity data available from EPA, which suggest that humans experience toxic effects only if they ingest tremendous amounts of nitrocellulose (i.e., amounts equivalent to 10% of our total diet) (EPA 1987b). For these reasons, ATSDR believes that long-term exposures to the estimated ambient air concentrations listed in Table 4 are not of public health concern.
To assess the public health implications of short-term exposures to the selected explosives, propellants, and fillers, ATSDR reviewed data published in its toxicological profiles, which are available for seven of the chemicals listed in Table 4 (ATSDR 1995a, 1995b, 1995c, 1995d, 1997, 1998, 2000). Limited data are available on acute inhalation toxicity associated with the chemicals that we researched, and most acute toxic effects were reported among occupational cohorts (e.g., employees of ammunition manufacturing plants), who likely were exposed to much greater levels of explosives, propellants, and fillers than were residents who live near SIAD. There is considerable uncertainty associated with our assessment of short-term exposures to explosives, propellants, and fillers, due to the lack of acute toxicity data. ATSDR notes, however, that the acute exposure levels to these chemicals are extremely lowsome much lower than can be measured with highly sensitive measurement devices. In summary, ATSDR finds that short-term exposures to the chemicals listed in Table 4 will be of extremely low magnitudes. We do not believe the exposures would be associated with adverse health effects, but this finding is based on limited acute toxicity data.
To assess long-term exposures, ATSDR compared the estimated concentrations for the chemical by-products of OB/OD events to their most sensitive health-based comparison value, considering both those derived for cancer and non-cancer outcomes. As Table 5 shows, for every chemical considered(7), the highest estimated air concentration in residential locations was lower than its corresponding comparison value. In fact, for the majority of these chemicals, estimated air concentrations were more than 1,000 times lower than health-based comparison values (i.e., levels that would require more detailed toxicologic evaluations in an ATSDR public health evaluation). Given this ample margin of safety, and ATSDR's belief that the modeling analysis includes several assumptions that likely overstate actual ambient air concentrations (see Appendix D.1), we conclude that long-term exposures to the chemical by-products of OB/OD events will not cause adverse health effects at any of the residential locations in the vicinity of SIAD.
To assess acute exposures, ATSDR limited its review to chemicals in Table 5 with estimated annual average air concentrations greater than 0.0001 g/m3. This decision was made to focus on the chemicals with the higher concentrations, while not considering those chemicals with air quality impacts that would be virtually impossible to measure in an ambient air monitoring study. After examining acute toxicity data for the selected chemicals (ammonia, benzene, carbon monoxide, hydrogen cyanide, nitric oxide, nitrogen dioxide, phenol, styrene, sulfur dioxide, toluene, and xylenes), ATSDR found that none of the estimated short-term concentrations exceeded levels of concern for acute toxicity.
Overall, our review focused on nearly 100 pollutants known to be emitted from OB/OD waste treatment operations. Whether considering reasonable estimates of ambient air concentrations or measured levels of air contamination, we did not identify any air contaminants that residents (both in California and Nevada) would breathe at levels that are harmful. In fact, for most pollutants examined, the estimated air concentrations were orders of magnitude lower than levels of potential health concern, whether for cancer or non-cancer effects.
ATSDR notes, however, that evaluating the potential effects of environmental contaminants on humans involves some uncertainty. For example, our analyses for many chemicals are based strictly on findings of a modeling analysis (Brown and Root Environmental 1996a), and not on measured levels of air pollution. However, as Appendix D.1 describes, ATSDR believes the modeling analysis likely overstated actual exposure concentrations. Further, the health effects that might result from exposure to complex mixtures of chemicals are largely not understood. Given these uncertainties, ATSDR conducted a separate environmental health evaluation based on an entirely different set of data (i.e., cancer registry data) to assess whether local residents have increased risks of developing cancer. This separate analysis is the subject of the next section. To reduce uncertainties in our evaluation, ATSDR recommends that additional PM10 sampling occur if SIAD conducts OB/OD waste treatment operations in the future, although we have no knowledge if these operations will ever resume.
1 Specifically, wind directions between southwest and northwest were considered to be "roughly from west to east," while wind directions between southeast and northeast were considered to be "roughly from east to west."
2 This estimate was calculated for fires that consume 1,000 acres of forest in a 24-hour period. Larger fires will have higher emission rates, and smaller fires will have lower ones.
3 In 2001, SIAD ceased its routine OB/OD operations, but the installation is still allowed to use OB/OD for emergency situations and national security reasons. Since 2001, SIAD has used OB/OD to treat very small quantities of ordnance and propellants, such as those believed to be unsafe to transport.
4 ATSDR notes that the contractors who performed the monitoring study concluded in their summary report that the monitoring may not have captured the highest air quality impacts from the OB/OD operations. ATSDR believes that conclusion was based on a flawed statistical analysis of the data. Appendix C.1 explains why ATSDR disagrees with the contractor's findings on the monitoring study.
5 These measured PM10 concentrations are 3-hour average samples collected during the time when OB/OD operations occurred. It is quite possible that the 24-hour average concentrations at these locations were considerably lower, because waste treatment occurred only during a few hours per day. However, 24-hour average PM10 levels were not measured at these sampling locations.
6 Aluminum and iron were selected for this comparison because they were detected more frequently than all other metals and inorganic compounds considered. Calculating average concentrations for these metals involves less uncertainty, since the data sets involve the fewest amount of non detects.
7 Eight chemicals in Table 5 do not have health-based comparison values. The estimated air concentration of methane is well below levels that would be viewed as a physical hazard, and the estimated concentrations of all other chemicals were lower than 0.00004 g/m3. Such trace levels would be extremely difficult to measure, even when using highly sensitive field sampling equipment. Despite the limited toxicological data for these chemicals, ATSDR doubts that exposures to the concentrations listed would cause any adverse health effect.
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